How to use std::unique_ptr on a struct?

The title says most of it, how do I do this? I've Googled around a bit and nothing has told me that it can't be done, but nothing has explained how to do it either.

Take this snippet of code here:

#include <cstdio>
#include <memory>

int main(void)
{
    struct a_struct
    {
        char first;
        int second;
        float third;
    };

    std::unique_ptr<a_struct> my_ptr(new a_struct);

    my_ptr.first = "A";
    my_ptr.second = 2;
    my_ptr.third = 3.00;

    printf("%c\n%i\n%f\n",my_ptr.first, my_ptr.second, my_ptr.third);

    return(0);
}

As the people who can answer this already know, this doesn't work, it doesn't even compile.

My question is how do I make something like this work?

The compilation error (using g++-7) looks like

baduniqueptr6.cpp: In function ‘int main()’:
baduniqueptr6.cpp:15:12: error: ‘class std::unique_ptr<main()::a_struct>’ has no member named ‘first’
     my_ptr.first = "A";
            ^~~~~
baduniqueptr6.cpp:16:12: error: ‘class std::unique_ptr<main()::a_struct>’ has no member named ‘second’
     my_ptr.second = 2;
            ^~~~~~
baduniqueptr6.cpp:17:12: error: ‘class std::unique_ptr<main()::a_struct>’ has no member named ‘third’
     my_ptr.third = 3.00;
            ^~~~~
baduniqueptr6.cpp:19:34: error: ‘class std::unique_ptr<main()::a_struct>’ has no member named ‘first’
     printf("%c\n%i\n%f\n",my_ptr.first, my_ptr.second, my_ptr.third);
                                  ^~~~~
baduniqueptr6.cpp:19:48: error: ‘class std::unique_ptr<main()::a_struct>’ has no member named ‘second’
     printf("%c\n%i\n%f\n",my_ptr.first, my_ptr.second, my_ptr.third);
                                                ^~~~~~
baduniqueptr6.cpp:19:63: error: ‘class std::unique_ptr<main()::a_struct>’ has no member named ‘third’
     printf("%c\n%i\n%f\n",my_ptr.first, my_ptr.second, my_ptr.third);
                                                               ^~~~~